In recent years, solar cells incorporating crystals known as perovskites have repeatedly broken records of how well they convert sunlight to electricity, suggesting they might help revolutionize photovoltaics. Now, a group of scientists have developed a way to recycle all parts of these solar cells in a more environmentally friendly way, compared to current methods. The recycled solar cells work as efficiently as the originals, the new study finds.
The most common solar cells use silicon to convert light to electricity. These silicon photovoltaics, which have been on the market for more than 30 years, are rapidly approaching their theoretical conversion efficiency limit of 29.4 percent. As of October 2024, the best lab cells had achieved efficiencies of more than 27 percent.
As first-generation silicon solar panels now reach the end of their life cycle, problems are mounting when it comes to recycling the panels in an economically viable and ecologically sound way. For instance, in older silicon solar modules, most recycling facilities actually trash the silicon, silver, and copper—their most valuable and least accessible materials—recovering only the aluminum frames and glass panes. Researchers are investigating better recycling methods that can recover at least 90 percent of these materials in the devices. However, these processes are expensive and often involve toxic chemicals.
The Promise of Perovskites
One of the most promising next-generation solar cell technologies involves perovskites. These crystals are not only relatively inexpensive and easy to manufacture, but also lightweight, flexible, and transparent. That transparency means perovskite and silicon can be stacked together in tandem solar cells, which achieved efficiencies of 34.6 percent in 2024.
However, perovskite solar cells might pose bigger problems when it comes to waste. They have shorter lifespans than their silicon counterparts, so they could build up in landfills more quickly. They also contain lead and pose an environmental risk, says Xun Xiao, a postdoctoral researcher in the department of physics, chemistry, and biology at Linköping University in Sweden.
Methods for dismantling perovskite solar cells already exist. However, these mostly involve a substance called dimethylformamide, a common ingredient in paint solvents. It is toxic, environmentally hazardous, and potentially carcinogenic.
Researchers developed a new water-based solvent to separate the components of perovskite solar cells for easy recycling.Thor Balkhed/Linköping University
Now scientists have developed a low-cost strategy for dismantling perovskite solar modules using more ecologically friendly solvents. Their layer-by-layer approach can recycle every part of the devices—the cover glass, metal electrodes, perovskite crystal powders, and the charge transport layers.
The key element of this new strategy is an aqueous solvent for dissolving perovskites. With the water-based solvent, the researchers…
Read full article: Recycling Next-Gen Solar Cells With Water
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The post “Recycling Next-Gen Solar Cells With Water” by Charles Q. Choi was published on 02/25/2025 by spectrum.ieee.org
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